Publication
Nano-multilayered ZrN‒Ag/Mo‒S‒N film design for stable anti-frictional performance at a wide range of temperatures
| datacite.subject.fos | Engenharia e Tecnologia | |
| datacite.subject.sdg | 09:Indústria, Inovação e Infraestruturas | |
| dc.contributor.author | Ju, Hongbo | |
| dc.contributor.author | Luan, Jing | |
| dc.contributor.author | Xu, Junhua | |
| dc.contributor.author | Cavaleiro, Albano | |
| dc.contributor.author | Evaristo, Manuel | |
| dc.contributor.author | Fernandes, Filipe | |
| dc.contributor.author | Fernandes, Filipe | |
| dc.date.accessioned | 2025-01-29T16:00:21Z | |
| dc.date.available | 2025-01-29T16:00:21Z | |
| dc.date.issued | 2024 | |
| dc.description.abstract | A multilayer film, composed by ZrN-Ag (20 nm) and Mo-S-N (10 nm) layers, combining the intrinsic lubricant characteristics of each layer was deposited using DC magnetron sputtering system, to promote lubrication in a wide-range of temperatures. The results showed that the ZrN-Ag/Mo-S-N multilayer film exhibited a sharp interface between the different layers. A face-centered cubic (fcc) dual-phases of ZrN and Ag co-existed in the ZrN-Ag layers, whilst the Mo-S-N layers displayed a mixture of hexagonal close-packed MoS2 (hcp-MoS2) nano-particles and an amorphous phase. The multilayer film exhibited excellent room temperature (RT) triblogical behavior, as compared to the individual monolayer film, due to the combination of a relative high hardness with the low friction properties of both layers. The reorientation of MoS2 parallel to the sliding direction also contributed to the enhanced anti-frictional performance at RT. At 400 °C, the reorientation of MoS2 as well as the formation of MoO3 phase were responsible for the lubrication, whilst the hard t-ZrO2 phase promoted abrasion and, consequently, led to increasing wear rate. At 600 °C, the Ag2MoO4 double-metal oxide was the responsible for the low friction and wear-resistance; furthermore, the observed transformation from t-ZrO2 to m-ZrO2, could also have contributed to the better tribological performance. | eng |
| dc.description.sponsorship | This work was supported by the National Natural Science Foundation of China (Nos. 52171071, 51801081, and 52071159), national funds through FCT of Portugal - Fundação para a Ciência e a Tecnologia, under a scientific contract of 2021.04115.CEECIND, and the project of UIDB/00285/2020, LA/0112/2020, MCTool21 - ref. “POCI-01-0247-FEDER-045940”cofinanced via FEDER and FCT-Fundação para a Ciência e a Tecnologia (COMPETE), Outstanding University Young Teachers of “Qing Lan Project” of Jiangsu Province of China, Excellent Talents of “Shenlan Project” of Jiangsu University of Science of China. The authors also thank Fanlin Kong and Yiping Wang for their support to investigate the TEM results. | |
| dc.identifier.citation | Ju, H., Luan, J., Xu, J. et al. Nano-multilayered ZrN-Ag/Mo-S-N film design for stable anti-frictional performance at a wide range of temperatures. Friction 12, 2826–2837 (2024). https://doi.org/10.1007/s40544-024-0943-y | |
| dc.identifier.doi | 10.1007/s40544-024-0943-y | |
| dc.identifier.issn | 2223-7690 | |
| dc.identifier.uri | http://hdl.handle.net/10400.22/29327 | |
| dc.language.iso | eng | |
| dc.peerreviewed | yes | |
| dc.publisher | Springer Nature | |
| dc.relation | Centre for Mechanical Enginnering, Materials and Processes | |
| dc.relation.hasversion | https://link.springer.com/article/10.1007/s40544-024-0943-y | |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | DC magnetron sputtering | |
| dc.subject | ZrN-Ag/Mo-S-N multilayer film | |
| dc.subject | Tribological properties | |
| dc.subject | tribo-phases | |
| dc.title | Nano-multilayered ZrN‒Ag/Mo‒S‒N film design for stable anti-frictional performance at a wide range of temperatures | eng |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.awardTitle | Centre for Mechanical Enginnering, Materials and Processes | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00285%2F2020/PT | |
| oaire.citation.endPage | 2837 | |
| oaire.citation.issue | 12 | |
| oaire.citation.startPage | 2826 | |
| oaire.citation.title | Friction | |
| oaire.citation.volume | 12 | |
| oaire.fundingStream | 6817 - DCRRNI ID | |
| oaire.version | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |
| person.familyName | Fernandes | |
| person.givenName | Filipe | |
| person.identifier | 995468 | |
| person.identifier.ciencia-id | 2113-A18B-EEE8 | |
| person.identifier.orcid | 0000-0003-4035-3241 | |
| person.identifier.scopus-author-id | 55644767300 | |
| project.funder.identifier | http://doi.org/10.13039/501100001871 | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
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