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Mechanical and thermal characterization of a structural polyurethane adhesive modified with thermally expandable particles

dc.contributor.authorBanea, Mariana D.
dc.contributor.authorSilva, Lucas F. M. da
dc.contributor.authorCarbas, Ricardo J.C.
dc.contributor.authorCampilho, Raul
dc.date.accessioned2015-01-05T11:46:24Z
dc.date.available2015-01-05T11:46:24Z
dc.date.issued2014
dc.description.abstractThermally expandable particles (TEPs) are used in a wide variety of applications by industry mainly for weight reduction and appearance improvement for thermoplastics, inks, and coatings. In adhesive bonding, TEPs have been used for recycling purposes. However, TEPs might be used to modify structural adhesives for other new purposes, such as: to increase the joint strength by creating an adhesive functionally modified along the overlap of the joint by gradual heating and/or to heal the adhesive in case of damage. In this study, the behaviour of a structural polyurethane adhesive modified with TEPs was investigated as a preliminary study for further investigations on the potential of TEPs in adhesive joints. Tensile bulk tests were performed to get the tensile properties of the unmodified and TEPs-modified adhesive, while Double Cantilever Beam (DCB) test was performed in order to evaluate the resistance to mode I crack propagation of unmodified and TEPs-modified adhesive. In addition, in order to investigate the behaviour of the particles while encapsulated in adhesives, a thermal analysis was done. Scanning electron microscopy (SEM) was used to examine the fracture surface morphology of the specimens. The fracture toughness of the TEPs-modified adhesive was found to increase by addition of TEPs, while the adhesive tensile strength at yield decreased. The temperature where the particles show the maximum expansion varied with TEPs concentration, decreasing with increasing the TEPs content.por
dc.identifier.doi10.1016/j.ijadhadh.2014.06.008
dc.identifier.urihttp://hdl.handle.net/10400.22/5276
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevierpor
dc.relation.ispartofseriesInternational Journal of Adhesion & Adhesives;Vol. 54
dc.relation.publisherversionhttp://www.sciencedirect.com/science/article/pii/S0143749614001341por
dc.subjectThermally expandable particles (TEPs)por
dc.subjectAdhesive jointspor
dc.subjectFracture toughnesspor
dc.titleMechanical and thermal characterization of a structural polyurethane adhesive modified with thermally expandable particlespor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage199por
oaire.citation.startPage191por
oaire.citation.titleInternational Journal of Adhesion & Adhesivespor
oaire.citation.volume54por
person.familyNameCampilho
person.givenNameRaul Duarte Salgueiral Gomes
person.identifier.ciencia-id0314-43B9-03D4
person.identifier.orcid0000-0003-4167-4434
rcaap.rightsclosedAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication4decb370-eb85-4ee1-987f-ec328565ea07
relation.isAuthorOfPublication.latestForDiscovery4decb370-eb85-4ee1-987f-ec328565ea07

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