Publication
Biomimetic norfloxacin sensors made of molecularly-imprinted materials for potentiometric transduction
| dc.contributor.author | Moreira, Felismina T. C. | |
| dc.contributor.author | Freitas, Victor | |
| dc.contributor.author | Sales, M. Goreti F. | |
| dc.date.accessioned | 2013-11-21T16:32:57Z | |
| dc.date.available | 2013-11-21T16:32:57Z | |
| dc.date.issued | 2011 | |
| dc.description.abstract | A biomimetic sensor for norfloxacin is presented that is based on host-guest interactions and potentiometric transduction. The artificial host was imprinted into polymers made from methacrylic acid and/or 2-vinyl pyridine. The resulting particles were entrapped in a plasticized poly(vinyl chloride) (PVC) matrix. The sensors exhibit near-Nernstian response in steady state evaluations, and detection limits range from 0.40 to 1.0 μgmL−1, respectively, and are independent of pH values at between 2 and 6, and 8 and 11, respectively. Good selectivity was observed over several potential interferents. In flowing media, the sensors exhibit fast response, a sensitivity of 68.2 mV per decade, a linear range from 79 μM to 2.5 mM, a detection limit of 20 μgmL−1, and a stable baseline. The sensors were successfully applied to field monitoring of norfloxacin in fish samples, biological samples, and pharmaceutical products | por |
| dc.identifier.doi | 10.1007/s00604-010-0464-4 | pt_PT |
| dc.identifier.uri | http://hdl.handle.net/10400.22/2900 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Springer | por |
| dc.relation.ispartofseries | Microchim Acta; Vol. 172, Issue 1-2 | |
| dc.relation.publisherversion | http://link.springer.com/article/10.1007%2Fs00604-010-0464-4 | por |
| dc.subject | Norfloxacin | por |
| dc.subject | Molecularly-imprinted sensors | por |
| dc.subject | Potentiometry | por |
| dc.subject | FIA | por |
| dc.subject | Fish | por |
| dc.title | Biomimetic norfloxacin sensors made of molecularly-imprinted materials for potentiometric transduction | por |
| dc.type | journal article | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 23 | por |
| oaire.citation.issue | Issue 1-2 | |
| oaire.citation.startPage | 15 | por |
| oaire.citation.title | Microchim Acta | |
| oaire.citation.volume | Vol. 172 | |
| person.familyName | Moreira | |
| person.givenName | Felismina | |
| person.identifier | 1589429 | |
| person.identifier.ciencia-id | C917-6A46-A270 | |
| person.identifier.orcid | 0000-0003-4237-8952 | |
| person.identifier.scopus-author-id | 23486193000 | |
| rcaap.rights | openAccess | por |
| rcaap.type | article | por |
| relation.isAuthorOfPublication | 9c13153d-a73a-49ff-b7f6-c9733bc6725e | |
| relation.isAuthorOfPublication.latestForDiscovery | 9c13153d-a73a-49ff-b7f6-c9733bc6725e |