Browsing by Author "Ribeiro, M.C.S."
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- A case study on the eco-efficiency performance of a composite processing industry: evaluation and quantification of potential improvementsPublication . Ribeiro, M.C.S.; Meira Castro, Ana C.; Silva, F.J.G.; Meixedo, JP; Oliveira, L.; Alvim, M.R.; Fiúza, A.; Dinis, M.L.In this study, an attempt was made in order to measure and evaluate the eco-efficiency performance of a pultruded composite processing company. For this purpose the recommendations of World Business Council for Sustainable Development (WCSD) and the directives of ISO 14301 standard were followed and applied. The main general indicators of eco-efficiency, as well as the specific indicators, were defined and determined. With basis on indicators’ figures, the value profile, the environmental profile, and the pertinent eco-efficiency ratios were established and analyzed. In order to evaluate potential improvements on company eco-performance, new indicators values and eco-efficiency ratios were estimated taking into account the implementation of new proceedings and procedures, at both upstream and downstream of the production process, namely: i) Adoption of a new heating system for pultrusion die-tool in the manufacturing process, more effective and with minor heat losses; ii) Recycling approach, with partial waste reuse of scrap material derived from manufacturing, cutting and assembly processes of GFRP profiles. These features lead to significant improvements on the sequent assessed eco-efficiency ratios of the present case study, yielding to a more sustainable product and manufacturing process of pultruded GFRP profiles.
- Characterization of hybrid pultruded structural products based on preformsPublication . Silva, F.J.G.; Baptista, Andresa; Pinto, Gustavo Filipe; Campilho, R.D.S.G.; Ribeiro, M.C.S.Pultrusion is a widely known technique for production of constant cross-section profiles, such as bars, L-shape or T-shape profiles, as well as structural tubes in polymer matrix composite materials. In some applications, requirements are demanding for profiles able to provide better thermal or sound insulation or needing a slightly higher moment of inertia without increasing the ratio between weight and strength. In such cases, hybrid pultruded profiles with core based on preforms are a possible solution. After obtaining prototypes according to the methodologies described in a previous work, and as a complement to that work, it is necessary to verify if the properties of these hybrid profiles correspond to the initial expectations, by performing destructive and non-destructive tests. Thus, tensile, compression and bending tests were performed, in order to verify the mechanical benefits achieved through the core introduction into the hollow profile and to analyse the added value brought by these new products. These values, once properly validated, can be added to existing databases related to structural calculation programs, enabling to get the adequate values for calculations regarding this kind of profiles. In addition, thermal and acoustic insulation tests were performed, in order to quantify the physical improvements achieved regarding these properties, which are extremely important in specific applications linked to the civil construction and public works, among many others. The cored profiles showed a strong adhesion between the profile and any kind of core tested as well as improved properties in terms of thermal insulation and moment of inertia. However, the sound insulation did not present significant improvements, probably due to GFRP profile external rigidity and consequent reflection.
- Design of experiments applied to the mix design process of polymer mortar materials modified with GFRP recyclatesPublication . Ribeiro, M.C.S.; Fiúza, A.; Dinis, M.L.; Meira Castro, Ana C.; Silva, F.J.G.; Meixedo, JPIn this work, the effect of incorporation of recycled glass fibre reinforced plastics (GFRP) waste materials, obtained by means of shredding and milling processes, on mechanical behavior of polyester polymer mortar (PM) materials was assessed. For this purpose, different contents of GFRP recyclates (between 4% up to 12% in mass), were incorporated into polyester PM materials as sand aggregates and filler replacements. The effect of silane coupling agent addition to resin binder was also evaluated. Applied waste material was proceeding from the shredding of the leftovers resultant from the cutting and assembly processes of GFRP pultrusion profiles. Currently, these leftovers, jointly with unfinished products and scrap resulting from pultrusion manufacturing process, are landfilled, with supplementary added costs. Thus, besides the evident environmental benefits, a viable and feasible solution for these wastes would also conduct to significant economic advantages. Design of experiments and data treatment were accomplish by means of full factorial design approach and analysis of variance ANOVA. Experimental results were promising toward the recyclability of GFRP waste materials as aggregates and reinforcement for PM materials, with significant improvements on mechanical properties with regard to non-modified formulations.
- Experiments on new polymer based mortars filled with FRP waste recyclates - a quantitative analysisPublication . Ribeiro, M.C.S.; Meixedo, JP; Meira Castro, Ana C.; Fiúza, A.; Dinis, M.L.; Silva, F.J.G.Glass fibre-reinforced plastics (GFRP) have been considered inherently difficult to recycle due to both: cross-linked nature of thermoset resins, which cannot be remolded, and complex composition of the composite itself. Presently, most of the GFRP waste is landfilled leading to negative environmental impacts and supplementary added costs. With an increasing awareness of environmental matters and the subsequent desire to save resources, recycling would convert an expensive waste disposal into a profitable reusable material. In this study, efforts were made in order to recycle grinded GFRP waste, proceeding from pultrusion production scrap, into new and sustainable composite materials. For this purpose, GFRP waste recyclates, were incorporated into polyester based mortars as fine aggregate and filler replacements at different load contents and particle size distributions. Potential recycling solution was assessed by mechanical behaviour of resultant GFRP waste modified polymer mortars. Results revealed that GFRP waste filled polymer mortars present improved flexural and compressive behaviour over unmodified polyester based mortars, thus indicating the feasibility of the waste reuse in polymer mortars and concrete. © 2011, Advanced Engineering Solutions.
- On the recyclability of glass fiber reinforced thermoset polymeric composites towards the sustainability of polymers' industryPublication . Ribeiro, M.C.S.; Dinis, M.L.; Meira Castro, Ana C.; Fiuza, A.; Meixedo, JP; Ferreira, A.; Alvim, M.R.Considering the added value of recycling solution assessed by an evaluation of flexural and compressive loading capacity of PC specimens modified with mechanically recycled GFRP wastes, as well as the inherent environmental and economic benefits, the incorporation of GFRP recyclates into PC materials has been revealed as a viable technological option for the sustainability of the GFRP polymers’ industry. Nevertheless, the recyclability of composite materials is complex and is sometimes seen as a key barrier to the adoption of these materials in some markets. One of the few successful applications, was developed by Reprocover, in Belgium, and it has been commercialized since 2011. In addition, the recently investigation line that was started and concerning the GFRP recyclates into PC materials also called the attention of Global Fiberglass SolutionsTM group. Even so, and although all the efforts that had been done on developing cost-effective recycling routes, GFRP wastes still remain mired by the scarceness of reliable outlet markets for the recyclates and clearly developed recycling paths between waste producers and potential consumers for the recyclates. However, it is foreseen that this scenario will change in the next few years as strong investments are being made in this field. The innovation in this field has just started, providing as this way a source of new opportunities.
- Recycling Approach towards Sustainability Advance of Composite Materials’ IndustryPublication . Ribeiro, M.C.S.; Fiuza, A.; Ferreira, A.; Dinis, M.L.; Meira Castro, Ana C.; Meixedo, JP; Alvim, M.R.Worldwide volume production and consumption of engineered composite materials, namely fiber reinforced polymers (FRP), have increased in the last decades, mostly in the construction, automobile, aeronautic and wind energy sectors. This rising production and consumption have also led to an increasing amount of FRP waste, either end-of-life (EoL) products or manufacturing rejects. Taking into account the actual and impending EU framework on waste management, in which clear targets are set with concrete measures to ensure effective implementation, landfill and incineration will be progressively unavailable as traditional end-routes for this kind of waste. Recycling techniques and end-use applications for the recyclates have been investigated over the past twenty years, but even so, more cost-effective and feasible market outlets for the recyclates should be identified that meet both the economic and the environmental points of view. This paper is aimed at enclosing and summarizing an update overview regarding all these issues: current legislation, recycling techniques and end-use applications for the recyclates. Additionally, as a case study, the assessment of the potential improvements that could be made on the eco-efficiency performance (sustainability) of a typical FRP composite materials’ industry by recycling and re-engineering process approaches is also reported.