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Determination of total petroleum hydrocarbons in soil from different locations using infrared spectrophotometry and gas chromatography

dc.contributor.authorPaíga, Paula
dc.contributor.authorMendes, Lurdes
dc.contributor.authorAlbergaria, José Tomás
dc.contributor.authorDelerue-Matos, Cristina
dc.date.accessioned2013-10-01T09:07:05Z
dc.date.available2013-10-01T09:07:05Z
dc.date.issued2012
dc.description.abstractTotal petroleum hydrocarbons (TPH) are important environmental contaminants which are toxic to human and environmental receptors. Several analytical methods have been used to quantify TPH levels in contaminated soils, specifically through infrared spectrometry (IR) and gas chromatography (GC). Despite being two of the most used techniques, some issues remain that have been inadequately studied: a) applicability of both techniques to soils contaminated with two distinct types of fuel (petrol and diesel), b) influence of the soil natural organic matter content on the results achieved by various analytical methods, and c) evaluation of the performance of both techniques in analyses of soils with different levels of contamination (presumably non-contaminated and potentially contaminated). The main objectives of this work were to answer these questions and to provide more complete information about the potentials and limitations of GC and IR techniques. The results led us to the following conclusions: a) IR analysis of soils contaminated with petrol is not suitable due to volatilisation losses, b) there is a significant influence of organic matter in IR analysis, and c) both techniques demonstrated the capacity to accurately quantify TPH in soils, irrespective of their contamination levels.por
dc.identifier.doi10.2478/s11696-012-0193-8pt_PT
dc.identifier.issn0366-6352
dc.identifier.urihttp://hdl.handle.net/10400.22/2041
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherSpringer Verlagpor
dc.relation.ispartofseriesChemical Papers; Vol. 66, Issue 8
dc.relation.publisherversionhttp://link.springer.com/article/10.2478%2Fs11696-012-0193-8por
dc.subjectTotal petroleum hydrocarbonspor
dc.subjectSoilpor
dc.subjectInfrared spectrophotometrypor
dc.subjectGas chromatographypor
dc.titleDetermination of total petroleum hydrocarbons in soil from different locations using infrared spectrophotometry and gas chromatographypor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage721por
oaire.citation.startPage711por
oaire.citation.volume66por
person.familyNamePaíga
person.familyNameDelerue-Matos
person.givenNamePaula
person.givenNameCristina
person.identifier1668889
person.identifier.ciencia-id331A-5D6A-D3C8
person.identifier.ciencia-id9A1A-43FB-5C27
person.identifier.orcid0000-0002-9593-1355
person.identifier.orcid0000-0002-3924-776X
person.identifier.ridQ-4930-2018
person.identifier.ridD-4990-2013
person.identifier.scopus-author-id6506638953
person.identifier.scopus-author-id6603741848
rcaap.rightsopenAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication4a0677dc-0b54-4831-aa9a-4a73f0df911d
relation.isAuthorOfPublication09f6a7bd-2f15-42b0-adc5-04bd22210519
relation.isAuthorOfPublication.latestForDiscovery09f6a7bd-2f15-42b0-adc5-04bd22210519

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