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Removal of Cd(II), Zn(II) and Pb(II) from aqueous solutions by brown marine macro algae: kinetic modelling

dc.contributor.authorFreitas, Olga M.
dc.contributor.authorMartins, Ramiro J. E
dc.contributor.authorDelerue-Matos, Cristina
dc.contributor.authorBoaventura, Rui
dc.date.accessioned2013-11-25T12:44:28Z
dc.date.available2013-11-25T12:44:28Z
dc.date.issued2008
dc.description.abstractSpecific marine macro algae species abundant at the Portuguese coast (Laminaria hyperborea, Bifurcaria bifurcata, Sargassum muticum and Fucus spiralis) were shown to be effective for removing toxic metals (Cd(II), Zn(II) and Pb(II)) from aqueous solutions. The initial metal concentrations in solution were about 75–100 mg L−1. The observed biosorption capacities for cadmium, zinc and lead ions were in the ranges of 23.9–39.5, 18.6–32.0 and 32.3–50.4 mg g−1, respectively. Kinetic studies revealed that the metal uptake rate was rather fast, with 75% of the total amount occurring in the first 10 min for all algal species. Experimental data were well fitted by a pseudo-second order rate equation. The contribution of internal diffusion mechanism was significant only to the initial biosorption stage. Results indicate that all the studied macro algae species can provide an efficient and cost-effective technology for eliminating heavy metals from industrial effluents.por
dc.identifier.doi10.1016/j.jhazmat.2007.08.081pt_PT
dc.identifier.issn0304-3894
dc.identifier.urihttp://hdl.handle.net/10400.22/2938
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevierpor
dc.relation.ispartofseriesJournal of Hazardous Materials; Vol. 153, Issue 1-2
dc.relation.publisherversionhttp://www.sciencedirect.com/science/article/pii/S030438940701271Xpor
dc.subjectBiosorptionpor
dc.subjectHeavy metalpor
dc.subjectMarine macro algaepor
dc.subjectKinetic modellingpor
dc.titleRemoval of Cd(II), Zn(II) and Pb(II) from aqueous solutions by brown marine macro algae: kinetic modellingpor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage501por
oaire.citation.issueIssue 1-2
oaire.citation.startPage493por
oaire.citation.volumeVol. 153
person.familyNameDelerue-Matos
person.givenNameCristina
person.identifier.ciencia-id9A1A-43FB-5C27
person.identifier.orcid0000-0002-3924-776X
person.identifier.ridD-4990-2013
person.identifier.scopus-author-id6603741848
rcaap.rightsopenAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication09f6a7bd-2f15-42b0-adc5-04bd22210519
relation.isAuthorOfPublication.latestForDiscovery09f6a7bd-2f15-42b0-adc5-04bd22210519

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