Logo do repositório
 
Publicação

Green zero-valent iron nanoparticles from Cistus ladanifer by-products for glyphosate remediation in water and soil

2026-06Artigo de investigação Acesso embargado
Ver registo simples
dc.contributor.authorFernandes, Filipe
dc.contributor.authorPaíga, Paula
dc.contributor.authorFreitas, Maria
dc.contributor.authorPinho, Cláudia
dc.contributor.authorOliveira, Ana Isabel
dc.contributor.authorDelerue-Matos, Cristina
dc.contributor.authorGrosso, Clara
dc.contributor.authorPinho, Cláudia
dc.contributor.authorOliveira, Ana Isabel
dc.date.accessioned2026-07-06T14:02:04Z
dc.date.available2026-07-06T14:02:04Z
dc.date.issued2026-06
dc.description.abstractFood and agricultural sectors produce large quantities of waste that present high potential for valorization. Cistus ladanifer L., used in the perfume and essential oil industries, produces post-distillation residues rich in phenolic compounds (PCs). These residues can be exploited for the green synthesis of nano zero-valent iron (nZVI), widely studied for environmental remediation. The aim of this study was to develop green synthesized nZVI using Abbreviations: AAE, Ascorbic acid equivalents; ABTS•+, 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid; AES, Analytical Eco-scale; AGREE, Analytical Greenness Calculator; AMPA, Aminomethylphosphonic acid; C-nZVI, Chemically synthesized nZVI; CLL, C. ladanifer leaves; CLS, C. ladanifer stems; DPPH•, 1,1- diphenyl-2-picrylhydrazyl; DLS, Dynamic light scattering; EDS, Energy-dispersive X-ray spectroscopy; EOs, Essential oils; FeCl3, Iron chloride; FMOC-Cl, 9-fluorenylmethyl chloroformate; FRAP, Ferric reducing antioxidant power assay; FTIR, Fourier-transform infrared spectroscopy; GAE, Gallic acid equivalents; GEMAM, Greenness evaluation metric for analytical methods; Glyph, Glyphosate; H2O, Water; HCl, Hydrochloric acid; HPLC, High-performance liquid chromatography; HPLC-FLD, High-performance liquid chromatography with fluorescence detection; LC-MS, Liquid chromatography-mass spectrometry; MeOH, Methanol; MES, Green Certificate Modified Eco-scale; MoGAPI, Modified Green Analytical Procedure Index; MRLs, Maximum residue levels; MTT, (3-(4,5-dimethylthiazol-2-yl)-2,5- diphenyltetrazolium bromide); NaBH4, Sodium borohydrate; nZVI, Nano zero-valent iron; NaOH, Sodium hydroxide; NNP, No nanoparticles; NPs, Nanoparticles; NS, No soil; PCs, Phenolic compounds; PDI, Polydispersity index; SEM, Scanning electron microscopy; SQUID, Superconducting quantum interference device; TG, Thermogravimetric analysis; TPC, Total phenolic content; XPS, X-ray photoelectron spectroscopy; XRD, X-ray diffraction; ZP, Zeta potential; Fe3O4, Magnetite; γ-Fe2O3, Maghemite; γ-FeO, Lepidocrocite.eng
dc.identifier.citationFernandes, F., Paíga, P., Freitas, M., Pinho, C., Oliveira, A. I., Delerue-Matos, C., & Grosso, C. (2026). Green zero-valent iron nanoparticles from Cistus ladanifer by-products for glyphosate remediation in water and soil. Bioresource Technology, 450, 134400. https://doi.org/10.1016/j.biortech.2026.134400
dc.identifier.doi10.1016/j.biortech.2026.134400
dc.identifier.eissn1873-2976
dc.identifier.issn0960-8524
dc.identifier.urihttp://hdl.handle.net/10400.22/32555
dc.language.isoeng
dc.peerreviewedyes
dc.publisherElsevier
dc.relationUID/50006/2025
dc.relation.hasversionhttps://www.sciencedirect.com/science/article/pii/S0960852426004815?via%3Dihub
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectAgrifood waste
dc.subjectNanoparticles
dc.titleGreen zero-valent iron nanoparticles from Cistus ladanifer by-products for glyphosate remediation in water and soileng
dc.typeresearch article
dspace.entity.typePublication
oaire.citation.titleBioresource Technology
oaire.citation.volume450
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85
person.familyNamePinho
person.familyNameOliveira
person.givenNameCláudia
person.givenNameAna Isabel
person.identifier.ciencia-id8B1B-A0D9-B6E4
person.identifier.ciencia-id9212-F501-E9EF
person.identifier.orcid0000-0002-3157-3712
person.identifier.orcid0000-0003-4420-6476
relation.isAuthorOfPublication01c994b8-cb20-43a8-947c-d2b978283944
relation.isAuthorOfPublication4b3fe293-2740-469f-97d3-99d0b107b5e0
relation.isAuthorOfPublication.latestForDiscovery01c994b8-cb20-43a8-947c-d2b978283944

Ficheiros

Principais
A mostrar 1 - 1 de 1
Miniatura indisponível
Nome:
ART_Cláudia Pinho.pdf
Tamanho:
6.05 MB
Formato:
Adobe Portable Document Format
Ver/Abrir
Licença
A mostrar 1 - 1 de 1
Miniatura indisponível
Nome:
license.txt
Tamanho:
4.03 KB
Formato:
Item-specific license agreed upon to submission
Descrição:
Ver/Abrir

Coleções

ESS - CISA/LAQV Requimte - Artigos