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New biomimetic sensors for the determination of tetracycline in biological samples: batch and flow mode operations

dc.contributor.authorMoreira, Felismina T. C.
dc.contributor.authorGuerreiro, J. Rafaela L.
dc.contributor.authorAzevedo, Vera Lúcia
dc.contributor.authorKamel, Ayman H.
dc.contributor.authorSales, M. Goreti F.
dc.date.accessioned2013-11-21T16:52:17Z
dc.date.available2013-11-21T16:52:17Z
dc.date.issued2010
dc.description.abstractNew potentiometric membrane sensors with cylindrical configuration for tetracycline (TC) are described based on the use of a newly designed molecularly imprinted polymer (MIP) material consisting of 2-vinylpyridine as a functional monomer in a plasticized PVC membrane. The sensor exhibited significantly enhanced response towards TC over the concentration range 1.59 10 5–1.0 10 3 mol L 1 at pH 3–5 with a lower detection limit of 1.29 10 5 mol L 1. The response was near-Nernstian, with average slopes of 63.9 mV decade 1. The effect of lipophilic salts and various foreign common ions were tested and were found to be negligible. The possibility of applying the proposed sensor to TC determination in spiked biological fluid samples was demonstrated.por
dc.identifier.doi10.1039/C0AY00511Hpt_PT
dc.identifier.urihttp://hdl.handle.net/10400.22/2902
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherThe Royal Society of Chemistrypor
dc.relation.ispartofseriesAnalytical Methods; Vol. 2, Issue 12
dc.relation.publisherversionhttp://pubs.rsc.org/en/Content/ArticleLanding/2010/AY/c0ay00511h#!divAbstractpor
dc.titleNew biomimetic sensors for the determination of tetracycline in biological samples: batch and flow mode operationspor
dc.typejournal article
dspace.entity.typePublication
oaire.citation.endPage2045por
oaire.citation.issueIssue 12
oaire.citation.startPage2039por
oaire.citation.titleAnalytical Methodspor
oaire.citation.volumeVol. 2por
person.familyNameMoreira
person.givenNameFelismina
person.identifier1589429
person.identifier.ciencia-idC917-6A46-A270
person.identifier.orcid0000-0003-4237-8952
person.identifier.scopus-author-id23486193000
rcaap.rightsopenAccesspor
rcaap.typearticlepor
relation.isAuthorOfPublication9c13153d-a73a-49ff-b7f6-c9733bc6725e
relation.isAuthorOfPublication.latestForDiscovery9c13153d-a73a-49ff-b7f6-c9733bc6725e

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