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- Hydrogeochemical, isotopical and ecotohicological approach to the Paranhos spring galleries catchworks from Porto urban area (nw Portugal)Publication . Guimarães, Laura; Afonso, Maria José; I. Chaminé, Helder; Marques, José M.; Carreira, Paula; Costa, Isilda; Teixeira, José; Guilhermino, Lúcia; Carvalho, José Martins; Fonseca, Paulo E.; Rocha. Fernando T.; Beleza, VitorinoThis multidisciplinary study presents the preliminary results of the hydrogeochemical, isotopical and ecotoxicological analyses performed to assess the nature and suitability for use of groundwater from the Paranhos’ spring galleries catchworks. These springs constituted for more than five centuries one of the main water supplies to Porto city. For the characterisation of the underground area (ca. 3km extension and a-25m of depth), constituted mainly by granitic rocks, the following tools were applied: i) subsurface geological and geotechnical mapping and; ii) hydrogeological, isotopical and ecotoxicological techniques. Surface and subsurface fieldwork surveys were first carried out to identify major tectonic accidents responsible for groundwater circulation paths and to assess lithological and structural heterogeneity. Hydrogeological fieldwork campaigns were then performed, and in situ determinations included: temperature (°C), pH and electrical conductivity (uS/cm). Several sampling sites were subsequently established, based on the surface activities located on the course of the springs, and water samples were collected for hydrogeochemical, isotopical and ecotoxicological analyses. All the water samples have been analysed for major element concentration. The isotopic techniques employed included d2H and d18O. For ecotoxicological evaluation standard acute bioassays with Daphnia magna were performed. For each sample, two 48h-LC5o bioassays were simultaneously performed: one with PH correction and the other without pH correction. In each bioassay, five concentrations of groundwater were prepared by dilution of the original sample with ASTM hard water. The hydrogeochemical analyses showed a nitrate and sulphate-enriched composition for these groundwaters, probably resulting from intense urbanisation, sewer leakage and some agricultural practices. Concerning the ecotoxicological analyses, no mortality was observed in any of the tests performed. The results obtained in this study suggest that part of Porto urban groundwater could be suitable for irrigation uses, but additional tests must be carried out to verify its compliance with existing standards of water quality. Specifically, geoenvironmental and ecotoxicological studies are required to assess potential variations in water composition and toxicity associated with seasonal changes in climate and human activities.
- A preliminary hydrogeologic conceptual model of the Manteigas-Nave de Santo Antonio-Torre sector (Serra da Estrela Natural park, central Portugal)Publication . Marques, Jorge Espinha; Marques, José M.; Carreira, Paula M.; I. Chaminé, Helder; Fonseca, Paulo E.; Samper, Javier; Pisani, B.; Alvares, D.; Vieira, Gonçalo T.; Mora, Carla; Teixeira, José; Gomes, Alberto; Carvalho, José Martins; Borges, Frederico S.; Rocha, Fernando T.; Beleza, VitorinoThis work is strongly connected with one of the most crucial water research issues at the turn of the millennium “High Mountain Areas Hydrology” (UNESCO IHP-VI Programme). Special emphasis is dedicated to high mountains and their role and impact on surface water/groundwater interaction at Serra da Estrela region - Central Portugal, in order propose a preliminary hydrogeologic conceptual model of the Manteigas - Nave de Santo Antonio - Torre sector, contributing to i) increase knowledge on recharge and discharge processes in this high mountain area and ii) assess the role of snowmelt as a source of groundwater resources, with the aid of coupled isotopic and geochemical techniques. The isotopic signatures of Caldas de Manteigas thermomineral waters combined with the i) morphostructural data and ii) isotopic composition of shallow groundwater and precipitation samples, made it possible to identify possible recharge areas, which should be located at altitude sites above 1500 m a.s.l.. The recharge altitudes are similar to those of Nave de Santo Antonio area which is directly located on the Braganca-Vilarica-Manteigas fault zone. This tectonic structure should play an important role in groundwater recharge and circulation towards the discharge zone at the Spas.
- Groundwater Favourable Infiltration Zones on Granitic Areas (Central Portugal)Publication . Carvalho, José Martins; Afonso, Maria José; Teixeira, José; Freitas, Liliana; Lopes, Ana Rita; Jesus, Rosário; Batista, Sofia; Carvalho, Rosário; Chaminé, Helder I.The Infiltration Potential Index (IPI) was used at Castelo Novo (Fundão, Central Portugal) to delineate favourable infiltration zones. The Infiltration Potential Index is a valuable tool to include in integrated water resources management in crystalline fractured rocks. An integrated approach combining hydrogeomorphology and GIS was developed applying multiple layers of information (tectonic lineaments, hydrogeological units, slope, drainage, land use, and precipitation). Different ranks were assigned to thematic layers and different weights were given to classes according to their contribution for groundwater using the Analytical Hierarchical Process (AHP) methodology. Almost 80% of the area is covered by slightly to moderately weathered (W1–2–W3) granite, having slopes of 5–15° and 15–25°, tectonic lineaments densities of 6–12 km/km2 and 12–18 km/km2 and drainage densities of 6–9 km/km2 and >9 km/km2. Scrub and/or herbaceous vegetation associations and bare rocks dominate. A moderate to high Infiltration Potential Index (IPI) is dominant in the area.
- Forecasting and Mass Transport Modelling of Nitrates in the Esposende–Vila Do Conde Nitrate Vulnerable Zone (Portugal)Publication . Zeferino, Joel; Carvalho, Maria Rosário; Ferreira, Tânia; Silva, Maria Catarina; Afonso, Maria José; Freitas, Liliana; Lopes, Ana Rita; Jesus, Rosário; Batista, Sofia; Chaminé, Helder I.; Carvalho, José MartinsEsposende–Vila do Conde, a nitrate-vulnerable zone, in the littoral north of Portugal, is contaminated by nitrates of an agricultural origin. Measures have been implemented to reduce that contamination. The effectiveness of the measures was evaluated, predicting the time required for the groundwater body reach the quality standard, i.e., less than 50 mg/L for dissolved nitrates. Two methodologies were used, groundwater flow and nitrates transport modelling, and predictive analysis of time series. The transient simulation of nitrate transport shows that the minimization measures imposed in the NVZ are being effective. However, the persistence of concentrations above 50 mg/L in some areas is notorious even in the next 24 years. The forecasting points out to a recovery period of ten years if current agricultural practices are maintained. The prediction of NO3 concentration based on forecasting methodology may not be applicable in the long run because it is a punctual analysis, not taking into consideration the contaminant dispersion dependent on the aquifer characteristics.