Publicação
Covalent organic framework assisted low-content ultrafine ru on porous N-doped carbon for efficient hydrogen evolution reaction
| datacite.subject.fos | Engenharia e Tecnologia::Engenharia Química | |
| datacite.subject.sdg | 09:Indústria, Inovação e Infraestruturas | |
| dc.contributor.author | Kong-Gang Qu | |
| dc.contributor.author | Zhi-Fei Chen | |
| dc.contributor.author | Li-Hui Wang | |
| dc.contributor.author | Hai-Bo Li | |
| dc.contributor.author | Su-Yuan Zeng | |
| dc.contributor.author | Rui Li | |
| dc.contributor.author | Li-Jian Meng | |
| dc.contributor.author | Hong-Yan Chen | |
| dc.contributor.author | Qing-Xia Yao | |
| dc.date.accessioned | 2025-04-03T13:47:45Z | |
| dc.date.available | 2025-04-03T13:47:45Z | |
| dc.date.issued | 2025 | |
| dc.description.abstract | (Excerpt) Pt-based materials are the benchmarked catalysts in the cathodic hydrogen evolution reaction (HER) of water splitting; the prohibitive cost and scarcity of Pt immensely impede the commercialization of hydrogen energy. Ru has aroused significant concern because of its Pt-like activity and much lower price. However, it’s still a top priority to minimize the Ru loading and pursue the most superior cost performance. Herein, N-rich covalent organic framework (COF) was employed to assist the preparation of ultrafine Ru, including nanoclusters and single atoms loaded onto porous N-doped carbon by a simple impregnation-pyrolysis process with a low Ru content of 6.60 wt%, exhibiting superior HER activity with mass activity of 21.86 and 11.52 A mg-1 Ru (@100 mV) in alkaline and acidic conditions, separately 14.7 and 2.12 times higher than that of commercial Pt/C. | eng |
| dc.description.sponsorship | This work was financially supported by the Development Project of Youth Innovation Team in Shandong Colleges and Universities (No. 2019KJC031), the Natural Science Foundation of Shandong Province (Nos. ZR2019MB064, ZR2021MB122 and ZR2022MB137) and the Doctoral Program of Liaocheng University (No. 318051608). | |
| dc.identifier.citation | Kong.Gang Qu, Zhi-Fei Chen, Li-Hui Wang, Hai-Bo Li, Su-Yuan Zeng, Rui Li, Li-Jian Meng, Hong-Yan Chen, & Qing-Xia Yao. (2025). Covalent organic framework assisted low-content ultrafine ru on porous N-doped carbon for efficient hydrogen evolution reaction. Rare Met., 44(3), 2094-2102. Springer Nature. https://doi.org/10.1007/s12598- 024-03024-w. | |
| dc.identifier.doi | https://doi.org/10.1007/s12598-024-03024-w | |
| dc.identifier.issn | 1001-0521 | |
| dc.identifier.issn | 1867-7185 | |
| dc.identifier.uri | http://hdl.handle.net/10400.22/29926 | |
| dc.language.iso | eng | |
| dc.peerreviewed | yes | |
| dc.publisher | Springer Nature | |
| dc.relation.hasversion | https://link.springer.com/article/10.1007/s12598-024-03024-w | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | |
| dc.subject | Covalent organic framework | |
| dc.subject | Ultrafine Ru | |
| dc.subject | Porous N-doped | |
| dc.subject | Hydrogen evolution reaction | |
| dc.title | Covalent organic framework assisted low-content ultrafine ru on porous N-doped carbon for efficient hydrogen evolution reaction | eng |
| dc.type | letter to the editor | |
| dspace.entity.type | Publication | |
| oaire.citation.endPage | 2102 | |
| oaire.citation.issue | 3 | |
| oaire.citation.startPage | 2094 | |
| oaire.citation.title | Rare Metals | |
| oaire.citation.volume | 44 | |
| oaire.version | http://purl.org/coar/version/c_970fb48d4fbd8a85 |