Browsing by Author "Ma, Bingyang"
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- Exploring tribological characteristics of ZrN-MoSN composite films fabricated via RF magnetron sputtering: Insights from microstructure and performance analysisPublication . Luan, Jing; Lu, Hongying; Xu, Junhua; Fernandes, Filipe; Fernandes, Filipe; Evaristo, Manuel; Ma, Bingyang; Xie, Fuxiang; Cavaleiro, Albano; Ju, HongboAchieving the stringent demands of sustainable tribological industrial applications poses a significant challenge, particular in optimizing the self-lubricant performance of nitride-based films. This paper tackled this challenge by designing and depositing a series of ZrN-MoSN composite films with varying (Mo + S)/Zr ratios, employing RF magnetron sputtering, aimed to enhance the tribological properties through utilizing the high loading capacity of the ZrN matrix and the exceptional self-lubricating attributes of Mo-S-N additives. After conducting thorough investigations on the microstructure, and tribological properties, the results revealed that the dense columnar structured ZrN-MoSN composite films displayed a polycrystalline composition comprising fcc-ZrN and hcp-MoS2 phases, intertwined with amorphous phases of Mo(SN)x and MoS2(N2). (Mo + S)/Zr ratios below 1.08 exhibited a minor impact on the room temperature (RT) tribological properties, while higher ratios led to degradation on RT average friction coefficient (COF) and wear rate (WR). However, the synergistic effect of ZrN matrix and the tribo-phases of layered MoO3 and hard ZrO2 contributed to the significant enhanced 500 °C tribological properties, particularly with an optimized (Mo + S)/Zr ratio of 0.43.
- Microstructure and Mechanical Properties of Magnetron Sputtering TiN-Ni Nanocrystalline Composite FilmsPublication . Ma, Bingyang; Yuan, Haitian; He, Zongqian; Shang, Hailong; Hou, Yanjie; Ju, Hongbo; Fernandes, FilipeIn this paper, TiN-Ni nanostructured composite films with different Ni contents are prepared using the magnetron sputtering method. The composition, microstructure, and mechanical properties of composite films are analyzed using an X-ray energy spectrometer (EDS), a scanning electron microscope (SEM), X-ray diffraction technology (XRD), a transmission electron microscope (TEM), and nanoindentation. All the films grow in a columnar crystal structure. There are only TiN diffraction peaks in the XRD spectrum, and no diffraction peaks of Ni and its compounds are observed. The addition of the Ni element disrupts the integrity of TiN lattice growth, resulting in a decrease in the grain size from 60 nm in TiN to 25 nm at 20.6% Ni. The film with a Ni content of 12.4 at.% forms a nanocomposite structure in which the nanocrystalline TiN phase (nc-TiN) is surrounded by the amorphous Ni (a-Ni) phase. The formation of nc-TiN/a-Ni nanocomposite structures relies on the good wettability of Ni on TiN ceramics. The hardness and elastic modulus of the film gradually decrease with the increase in Ni content, but the toughness is improved. The hardness and elastic modulus decrease from 19.9 GPa and 239.5 GPa for TiN film to 15.4 GPa and 223 GPa at 20.6 at.% Ni film, respectively, while the fracture toughness increases from 1.5 MPa m1/2 to 2.0 MPa m1/2. The soft and ductile Ni phase enriched at the TiN grain boundaries hinders the propagation of cracks in the TiN phase, resulting in a significant increase in the film’s toughness. The research results of this paper provide support for the design of TiN-Ni films with high strength and toughness and the understanding of the formation mechanism of nanocomposite structures.
- Microstructure evolution and mechanical behavior of magnetron sputtering AlN–Al nanostructured composite filmPublication . Ma, Bingyang; Sun, Boyuan; Li, Rongbin; Cao, Haoxin; Fernades, Filipe; Fernandes, FilipeIn this paper, a series of AlN–Al nanocomposite films are prepared by reactive magnetron sputtering. The effects of N2 flow rate on the microstructure and mechanical properties of the films are studied. The formation and evolution mechanism of the nanocomposite structure are revealed. The results show that with the decrease of N2 flow rate, the microstructure goes through three stages: pure AlN, amorphous Al surrounded nanocrystalline AlN and AlN nanoparticle reinforced Al matrix composite. Benefiting from the good wettability of Al on AlN ceramics, the film deposited at 6 sccm N2 flow rate forms a nanocomposite structure of about 8 nm AlN grains wrapped by 1–2 nm amorphous Al. The hardness of the films increases first and then decreases with the decrease of N2 flow rate, ranging from 4 GPa to 25 GPa. The toughness of the films is analyzed by the ratio of H/E, H3/E2, the normalized plastic depth (δH) and the morphology of large load indentation. The results show that the toughness of the nanocomposite film obtained at 6 sccm N2 flow rate is significantly improved while maintaining the hardness equivalent to that of pure AlN film. The improvement in toughness comes from the microcracks initiated in AlN hindered by the surrounding Al phase.
- RF magnetron sputtered Nb–V–N composite coatings for high-temperature self-lubricant applicationsPublication . Athmani, Moussa; Kong, FanLin; Ju, Hongbo; Luan, Jing; Zhang, Chengke; Ma, Bingyang; Cavaleiro, Albano; Fernades, Filipe; Fernandes, FilipeEnhancing the tribological properties of hard ceramic coatings for high temperature applications is one of the hot topics in the solid lubricant field. In this paper, a series of Nb–V–N coatings with different V concentrations were deposited using RF magnetron sputtering system, and the crystalline structure, mechanical and tribological properties were investigated. Results showed that the Nb–V–N coatings regardless of V concentrations exhibited two phase fcc-NbN with V in solid solution and hcp-NbN phase. The hardness and elastic modulus of the coatings were enhanced by adding 5.3 at.% of V. The room temperature tribological properties of the coatings were improved by the addition of V well due to the enhanced mechanical properties and the nature excellent self-lubricant characteristics. The evaluation of main tribophase from the wear track at elevated temperatures from the self-lubricant V2O3 at 400 °C to the V2O5 at 800 °C, contributed to the stable and excellent anti-frictional properties of the coating with a V concentration of 12.4 at.%. However, the wear rate of the coatings drops gradually with the increase of V concentrations due to the large amount of soft but lubricant tribophases at elevated temperatures.