Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.22/5615
Título: Comparison of Disposable Pipette Extraction and Dispersive Solid-Phase Extraction in the QuEChERS Method for Analysis of Pesticides in Strawberries
Autor: Fernandes, Virgínia C.
Domingues, Valentina F.
Mateus, Nuno
Delerue-Matos, Cristina
Data: Nov-2014
Editora: Oxford University Press
Relatório da Série N.º: Journal of Chromatographic Science;Vol. 52, Issue 10
Resumo: In this study, we sought to assess the applicability of GC–MS/MS for the identification and quantification of 36 pesticides in strawberry from integrated pest management (IPM) and organic farming (OF). Citrate versions of QuEChERS (quick, easy, cheap, effective, rugged and safe) using dispersive solid-phase extraction (d-SPE) and disposable pipette extraction (DPX) for cleanup were compared for pesticide extraction. For cleanup, a combination of MgSO4, primary secondary amine and C18 was used for both the versions. Significant differences were observed in recovery results between the two sample preparation versions (DPX and d-SPE). Overall, 86% of the pesticides achieved recoveries (three spiking levels 10, 50 and 200 µg/kg) in the range of 70–120%, with <13% RSD. The matrix effects were also evaluated in both the versions and in strawberries from different crop types. Although not evidencing significant differences between the two methodologies were observed, however, the DPX cleanup proved to be a faster technique and easy to execute. The results indicate that QuEChERS with d-SPE and DPX and GC–MS/MS analysis achieved reliable quantification and identification of 36 pesticide residues in strawberries from OF and IPM.
Peer review: yes
URI: http://hdl.handle.net/10400.22/5615
DOI: 10.1093/chromsci/bmu003
Versão do Editor: http://chromsci.oxfordjournals.org/content/52/10/1339
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