Utilize este identificador para referenciar este registo: http://hdl.handle.net/10400.22/10240
Título: Enhanced host–guest electrochemical recognition of herbicide MCPA using a b-cyclodextrin carbon nanotube sensor
Autor: Rahemi, V.
Vandamme, J.J.
Garrido, J.M.P.J.
Borges, F.
Brett, C.M.A.
Garrido, E.M.P.J.
Palavras-chave: Herbicides
Voltammetric sensors
Modified electrodes
Carbon nanotubes
Data: 2012
Editora: Elsevier
Relatório da Série N.º: Talanta;Vol. 99
Resumo: An electrochemical sensor for the determination of the chlorophenoxy herbicide MCPA has been developed, based on a combination of multi-walled carbon nanotubes with incorporated b-cyclodextrin and a polyaniline film modified glassy carbon electrode. The proposed molecular host–guest recogni-tion based sensor has a high electrochemical sensitivity for the determination of MCPA. The electrochemical behaviour of MCPA at the chemically modified electrode was investigated in detail by cyclic voltammetry. The results indicate that the b-CD/MWCNT modified glassy carbon electrode exhibits efficient electrocatalytic oxidation of MCPA with high sensitivity, stability and lifetime. The analytical characteristics of this film were used for the quantitative determination of MCPA in natural waters. Cyclic voltammetry in phosphate buffer solution at pH 6.0, allowed the development of a method to determine MCPA, without any previous steps of extraction, clean-up, or derivatization, in the range of 10–100 mmol L-1, with a detection limit of 0.99 mmol L-1 in water. The results were statistically compared with those obtained through an established high-performance liquid chromato-graphy technique, no significant differences having been found between the two methods.
URI: http://hdl.handle.net/10400.22/10240
DOI: https://doi.org/10.1016/j.talanta.2012.05.053
Versão do Editor: http://www.sciencedirect.com/science/article/pii/S003991401200433X
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